A continuum framework for grain boundary diffusion in thin film/substrate systems

A two-dimensional continuum model is developed for stress relaxation in thin films through grain boundary (GB) diffusion. When a thin film with columnar grains is subjected to thermal stress, stress gradients along the GBs are relaxed by diffusion of material from the film surface into the GBs. The transported material constitutes a wedge and becomes the source of stress inside the adjacent elastic grains that are perfectly bonded to the substrate. In the model, the coupling between diffusion and elasticity is obtained by numerically solving the governing equations in a staggered manner. A finite difference scheme is used to solve the diffusion equations, modified in order to implement realistic boundary conditions, while the elasticity problem is solved with the finite element method. The solutions reveal the existence of a universal power law scaling between the unrelaxed fraction of stress and the grain aspect ratio. For slender grains, the GB wedge attains a more uniform shape and relaxation is more effective. The kinetics of the process depends not only on the grain aspect ratio but also strongly on the thickness of the film. In case there is no adhesion between film and substrate, complete stress relaxation is attained albeit at a slightly slower rate. © 2010 American Institute of Physics

Combined effects of stress and temperature on hydrogen diffusion in non-hydride forming alloys applied in gas turbines

Hydrogen plays a vital role in the utilisation of renewable energy, but ingress and diffusion of hydrogen in a gas turbine can induce hydrogen embrittlement on its metallic components. This paper aims to investigate the hydrogen transport in a non-hydride forming alloy such as Alloy 690 used in gas turbines inspired by service conditions of turbine blades, i.e. under the combined effects of stress and temperature. An appropriate hydrogen transport equation is formulated, accounting for both stress and temperature distributions of the domain in the non-hydride forming alloy. Finite element (FE) analyses are performed to predict steady-state hydrogen distribution in lattice sites and dislocation traps of a double notched specimen under constant tensile load and various temperature fields. Results demonstrate that the lattice hydrogen concentration is very sensitive to the temperature gradients, whilst the stress concentration only slightly increases local lattice hydrogen concentration. The combined effects of stress and temperature result in the highest concentration of the dislocation trapped hydrogen in low-temperature regions, although the plastic strain is only at a moderate level. Our results suggest that temperature gradients and stress concentrations in turbine blades due to cooling channels and holes make the relatively low-temperature regions susceptible to hydrogen embrittlement

İri hacimli metalik camlarda cam oluşturma yeteneğinin teorik ve deneysel yöntemlerle incelenmesi

In this study molecular dynamics simulation program in NVT ensemble using Velocity Verlet integration was written in order to investigate the glass forming ability of two metallic systems. The Zn-Mg system, one of the frontiers of simple metal-metal metallic glasses and Fe-B, inquiring attention due to presence of many bulk glass forming alloy systems evolved from this binary with different alloying element additions. In addition to this, atomistic calculations on the basis of ordering were carried out for both Zn-Mg and Fe-B systems. Ordering energy values are calculated using electronic theory of alloys in pseudopotential approximation and elements which increase the ordering energy between atoms were determined. The elements which increase the ordering energy most were selected as candidate elements in order to design bulk amorphous alloy systems. In the experimental branch of the study centrifugal casting experiments were done in order to see the validity of atomistic calculations. Industrial low grade ferroboron was used as the master alloy and pure element additions were performed in order to constitute selected compositions. Fe62B21Mo5W2Zr6 alloy was successfully vitrified in bulk form using nearly conventional centrifugal casting processing. Specimens produced were characterized using SEM, XRD, and DSC in order to detect the amorphous structure and also the crystalline counterpart of the structure when the cooling rate is lower. Sequential peritectic and eutectic reaction pattern was found to be important for metallic glasses which can be vitrified in bulk forms with nearly conventional solidification methods.M.S. - Master of Scienc

Alteration of mean platelet volume in the pathogenesis of acute ischemic stroke: cause or consequence?

PMID = 2946590

On the sufficient symmetry conditions for isotropy of elastic moduli

The structural symmetry of a material can be manifested at a multitude of length scales such as spatial arrangement of atoms in a crystal structure, preferred orientation of grains in a polycrystalline material, alignment of reinforcing particles/fibers in composites or the micro-architecture of members in cellular solids. This paper proofs, in a simple yet rigorous manner, that six axes of fivefold structural symmetry is necessary and sufficient for isotropy of the elastic moduli tensor in the three-dimensional (3D) context. © VC 2018 by ASME